In order for Chrome or any browser to be able to scan your QR code from your recovery kit you need to enable "Screensharing" in the Privacy settings on your computer.
On your Mac:
1) System Preferences
2) Security & Privacy
3) Scroll down to Screen Recording
4) Click to enable Chrome
5) Follow prompt to close and reopen Chrome to enable settings update
6) Go back to Add device with QR code
4) Allow apps to access your pictures library -> On
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